We present ground-based spectroscopic verification of six Y dwarfs (see Cushing et al), eighty-nine T dwarfs, eight L dwarfs, and one M dwarf identified by the Wide-field Infrared Survey Explorer (WISE). Eighty of these are cold brown dwarfs with spectral types greater than or equal to T6, six of which have been announced earlier in Mainzer et al and Burgasser et al. We present color-color and color-type diagrams showing the locus of M, L, T, and Y dwarfs in WISE color space. Near-infrared classifications as late as early Y are presented and objects with peculiar spectra are discussed. After deriving an absolute WISE 4.6 um (W2) magnitude vs. spectral type relation, we estimate spectrophotometric distances to our discoveries. We also use available astrometric measurements to provide preliminary trigonometric parallaxes to four our discoveries, which have types of L9 pec (red), T8, T9, and Y0; all of these lie within 10 pc of the Sun. The Y0 dwarf, WISE 1541-2250, is the closest at 2.8 (+1.3,-0.6) pc; if this 2.8 pc value persists after continued monitoring, WISE 1541-2250 will become the seventh closest stellar system to the Sun. Another ten objects, with types between T6 and >Y0, have spectrophotometric distance estimates also placing them within 10 pc. The closest of these, the T6 dwarf WISE 1506+7027, is believed to fall at a distance of roughly 4.9 pc. WISE multi-epoch positions supplemented with positional info primarily from Spitzer/IRAC allow us to calculate proper motions and tangential velocities for roughly one half of the new discoveries. This work represents the first step by WISE to complete a full-sky, volume-limited census of late-T and Y dwarfs. Using early results from this census, we present preliminary, lower limits to the space density of these objects and discuss constraints on both the functional form of the mass function and the low-mass limit of star formation.

We have conducted a 4030-square-deg near-infrared proper motion survey using multi-epoch data from the Two Micron All-Sky Survey (2MASS). We find 2778 proper motion candidates, 647 of which are not listed in SIMBAD. After comparison to DSS images, we find that 107 of our proper motion candidates lack counterparts at B-, R-, and I-bands and are thus 2MASS-only detections. We present results of spectroscopic follow-up of 188 targets that include the infrared-only sources along with selected optical-counterpart sources with faint reduced proper motions or interesting colors. We also establish a set of near-infrared spectroscopic standards with which to anchor near-infrared classifications for our objects. Among the discoveries are six young field brown dwarfs, five "red L" dwarfs, three L-type subdwarfs, twelve M-type subdwarfs, eight "blue L" dwarfs, and several T dwarfs. We further refine the definitions of these exotic classes to aid future identification of similar objects. We examine their kinematics and find that both the "blue L" and "red L" dwarfs appear to be drawn from a relatively old population. This survey provides a glimpse of the kinds of research that will be possible through time-domain infrared projects such as the UKIDSS Large Area Survey, various VISTA surveys, and WISE, and also through z- or y-band enabled, multi-epoch surveys such as Pan-STARRS and LSST.