Jülich Centre for Neutron Science
We report resonant elastic X-ray scattering (REXS) of long-range magnetic order in EuPtSi3_{\text{3}}, combining different scattering geometries with full linear polarization analysis to unambiguously identify magnetic scattering contributions. At low temperatures, EuPtSi3_{\text{3}} stabilizes type A antiferromagnetism featuring various long-wavelength modulations. For magnetic fields applied in the hard magnetic basal plane, well-defined regimes of cycloidal, conical, and fan-like superstructures may be distinguished that encompass a pocket of commensurate type A order without superstructure. For magnetic field applied along the easy axis, the phase diagram comprises the cycloidal and conical superstructures only. Highlighting the power of polarized REXS, our results reveal a combination of magnetic phases that suggest a highly unusual competition between antiferromagnetic exchange interactions with Dzyaloshinsky--Moriya spin--orbit coupling of similar strength.
Nd-based pyrochlore oxides of the form Nd2B2_{2}B_{2}O7_{7} have garnered a significant amount of interest owing to the moment fragmentation physics observed in Nd2_{2}Zr2_{2}O7_{7} and speculated in Nd2_{2}Hf2_{2}O7_{7}. Notably this phenomenon is not ubiquitous in this family, as it is absent in Nd2_{2}Sn2_{2}O7_{7}, which features a smaller ionic radius on the BB-site. Here, we explore the necessary conditions for moment fragmentation in the Nd pyrochlore family through a detailed study of the mixed BB-site pyrochlore Nd2_{2}GaSbO7_{7}. The BB-site of this system is characterized by significant disorder and an extremely small average ionic radius. Similarly to Nd2_{2}Sn2_{2}O7_{7}, we find no evidence for moment fragmentation through our bulk characterization and neutron scattering experiments, indicating that chemical pressure (and not necessarily the BB-site disorder) plays a key role in the presence or absence of this phenomenon in this material family. Surprisingly, the presence of significant BB-site disorder in Nd2_{2}GaSbO7_{7} does not generate a spin glass ground state and instead the same all-in-all-out magnetic order identified in other Nd pyrochlores is found here.
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