From 01- to 15-Aug-2025 UT, the SPHEREx spacecraft observed interstellar object 3I/ATLAS. Using
R=40-
130 spectrophotometry at
λ=0.7-
5μm, light curves, spectra, and imaging of 3I were obtained. From these, robust detections of water gas emission at
2.7-
2.8μm and CO
2 gas at
4.23-
4.27μm plus tentative detections of
13CO
2 and CO gas were found. A slightly extended H
2O coma was detected, and a huge CO
2 atmosphere extending out to at least
4.2×105km was discovered. Gas production rates for H
2O,
12CO
2,
13CO
2, and CO were
Qgas=3.2×1026±20%,
1.6×1027±10%,
1.3×1025±25%, and
1.0×1026±25%, respectively. Co-addition of all
λ=1.0-
1.5μm scattered light continuum images produced a high SNR image consistent with an unresolved source. The scattered light lightcurve showed
≲15% variability over the observation period. The absolute brightness of 3I at
1.0-
1.5μm is consistent with a
< 2.5\,km radius nucleus surrounded by a 100 times brighter coma. The
1.5-
4.0μm continuum structure shows a strong feature commensurate with water ice absorption seen in KBOs and distant comets. The observed cometary behavior of 3I, including its preponderance of CO
2 emission, lack of CO output, small size, and predominance of large icy chunks of material in a flux-dominant coma is reminiscent of the behavior of short period comet 103P/Hartley 2, target of the NASA Deep Impact extended mission in 2010 and a ``hyperactive comet'' near the end of its outgassing lifetime. This correspondence places 3I closer to barely- or non-active 1I/Oumuamua than primitive, ice rich 2I/Borisov, suggesting that ISOs are often highly thermally processed before ejection into the ISM.