We discuss the first law of thermodynamics of Bardeen black hole. The presence of magnetic monopole charge modifies the energy and we define the temperature of the system accordingly. We introduce a lower cut-off to the space time by introducing a spherical surface, which can be identified with the event horizon. The corresponding temperature is identified with Hawking temperature. The entropy is assumed to obey the area law and we confirm this by calculating the statistical entropy by using brick wall model.

An optically high-quality single crystal of sodium mesitylene sulfonate crystal was successfully grown by a slow evaporation method using methanol as solvent at room temperature. Single-crystal XRD has characterized the material and belongs to a monoclinic structure with a C2 space group. Functional groups were determined using Fourier-transformed infrared spectroscopy. The optical quality of the generated crystal was evaluated using UV-Vis NIR spectral analysis, which is transparent in the range of 300-1500 nm. We report the optical properties using terahertz time-domain spectroscopy (THz-TDS) and THz generation using crystal.