Spallation Neutron Source Science Center
Beyond conventional ferromagnetism and antiferromagnetism, altermagnetism is a recently discovered unconventional magnetic phase characterized by time-reversal symmetry breaking and spin-split band structures in materials with zero net magnetization. This distinct magnetic phase not only enriches the understanding of fundamental physical concepts but also has profound impacts on condense-matter physics research and practical device applications. Spin-polarized band structures have been recently observed in semiconductors MnTe and MnTe2 with vanishing net magnetization, confirming the existence of this unconventional magnetic order. Metallic altermagnets have unique advantages for exploring novel physical phenomena related to low-energy quasiparticle excitations and for applications in spintronics as electrical conductivity in metals allows the direct manipulation of spin current through electric field. Here, through comprehensive characterization and analysis of the magnetic and electronic structures of KV2Se2O, we have unambiguously demonstrated a metallic room-temperature altermaget with d-wave spin-momentum locking. The highly anisotropic spin-polarized Fermi surfaces and the spin-density-wave order emerging in the altermagnetic phase make it an extraordinary platform for designing high-performance spintronic devices and studying many-body effects coupled with the unconventional magnetism.
The S=1/2S=1/2 antiferromagnetic Heisenberg chain is a paradigmatic quantum system hosting exotic excitations such as spinons and solitons, and forming random singlet state in the presence of quenched disorder. Realizing and distinguishing these excitations in a single material remains a significant challenge. Using nuclear magnetic resonance (NMR) on a high-quality single crystal of copper benzoate, we identify and characterize all three excitation types by tuning the magnetic field at ultra-low temperatures. At a low field of 0.2 T, a temperature-independent spin-lattice relaxation rate (1/T11/T_1) over more than a decade confirms the presence of spinons. Below 0.4 K, an additional relaxation channel emerges, characterized by 1/T1T1/T_1 \propto T and a spectral weight growing as ln(T/T0)-\ln(T/T_0), signaling a random-singlet ground state induced by weak quenched disorder. At fields above 0.5 T, a field-induced spin gap ΔH2/3\Delta \propto H^{2/3} observed in both 1/T11/T_1 and the Knight shift signifies soliton excitations. Our results establish copper benzoate as a unique experimental platform for studying one-dimensional quantum integrability and the interplay of disorder and correlations.
Determination of the magnetic structure and confirmation of the presence or absence of inversion (P\mathcal{P}) and time reversal (T\mathcal{T}) symmetry is imperative for correctly understanding the topological magnetic materials. Here high-quality single crystals of the layered manganese pnictide CaMnSb2_2 are synthesized using the self-flux method. De Haas-van Alphen oscillations indicate a nontrivial Berry phase of \sim π\pi and a notably small cyclotron effective mass, supporting the Dirac semimetal nature of CaMnSb2_2. Neutron diffraction measurements identify a C-type antiferromagnetic (AFM) structure below TNT\rm_{N} = 303(1) K with the Mn moments aligned along the aa axis, which is well supported by the density functional theory (DFT) calculations. The corresponding magnetic space group is PnmaPn'm'a', preserving a P×T\mathcal{P}\times\mathcal{T} symmetry. Adopting the experimentally determined magnetic structure, band crossings near the Y point in momentum space and linear dispersions of the Sb 5py,z5p_{y,z} bands are revealed by the DFT calculations. Furthermore, our study predicts the possible existence of an intrinsic second-order nonlinear Hall effect in CaMnSb2_2, offering a promising platform to study the impact of topological properties on nonlinear electrical transports in antiferromagnets.
Non-destructive characterization of lithium-ion batteries provides critical insights for optimizing performance and lifespan while preserving structural integrity. Optimizing electrolyte design in commercial LIBs requires consideration of composition, electrolyte-to-capacity ratio, spatial distribution, and associated degradation pathways. However, existing non-destructive methods for studying electrolyte infiltration, distribution, and degradation in LIBs lack the spatiotemporal resolution required for precise observation and quantification of the electrolyte. In this study, we employ neutron imaging with sufficient spatial resolution ~150 um and large field of view 20x20 cm2 to quantitatively resolve the electrolyte inventory and distribution within LiFePO4/graphite pouch cells under high-temperature accelerated aging. Quantitative standard curves based on neutron transmission attenuation reveal a clear electrolyte dry-out threshold at 3.18 g Ah-1 and the two stages evolutions of EI during cell aging were quantified. By integrating non-destructive electrochemical diagnostics, accelerated graphite material loss and liquid phase Li+ diffusion degradation is observed during pore-drying. Further analysis, including operando cyclic aging, reveals that the neutron transmission below the saturation reference is due to the enrichment of hydrogen nuclei within the solid-electrolyte interphase. Assumed pore-drying does not occur, the SEI signal of the electrodes can be quantitatively decoupled during ageing. Combined analyses with NI, TOF-SIMS, and SEM reveal that high EI cells exhibit uniform SEI growth and reduced degradation, while low EI cells show uneven SEI formation, accelerating capacity loss. This study unveils a dynamic electrolyte infiltration-consumption-dry-out process in LIBs, offering non-destructive and quantitative insights to guide sustainable and durable battery development.
BzScope is a Python package designed for efficiently calculating absolute cross sections of neutron-phonon inelastic scattering for crystalline powders in large phase spaces, addressing the limitations of traditional histogramming techniques in reproducing sharp structures and ensuring convergence. The package employs an adapted integral method and supports calculations of single- and two-phonon scattering functions in ideal crystalline powders, with numerical robustness up to a momentum transfer of 100 Ang^-1. Higher order scatterings up to several hundred orders are calculated by incoherent approximation in a well-established thermal neutron scattering physics package, NCrystal. In addition, a NCrystal plugin is made available for NCrystal-enabled Monte Carlo packages, facilitating direct comparison between the new physics and experimental data. Validation against NCrystal demonstrates good agreement in incoherent scattering for cubic systems Ni. In addition, it shows improved accuracy for low-symmetry materials NiP2NiP_2 by avoiding the isotropic atomic displacement approximations in NCrystal. Benchmarks the experimental differential cross section of LiH and total cross section of Be confirm its reliability. BzScope integrates with NCrystal via a plugin and therefore can be directly used in any NCrystal-enabled Monte Carlo package. This tool enhances the efficiency and accuracy of neutron scattering simulations, advancing the study of condensed matter dynamics.
As a fundamental physical phenomenon, achieving and controlling a large anomalous Hall effect (AHE) is crucial for advancing the understanding of topological physics and for developing applied technologies in spintronics. The recently discovered topological Kagome metal AAV3_3Sb5_5 (A=A = K, Rb, Cs)exhibits a significant AHE along with charge density wave (CDW) and superconductivity, providing an ideal platform to study the interactions between nontrivial band topology, CDW, and superconductivity. In this study, we systematically investigated the evolution of CDW, superconductivity, and AHE in electron (Mn)-doped Cs(V1x_{1-x}Mnx_x)3_3Sb5_5 single crystals. The experimental results show that electron doping rapidly suppresses superconductivity, while the CDW order remains relatively robust. Meanwhile, a significantly enhanced AHE, with a maximum anomalous Hall conductivity (AHC) of ~25331 \Ohm ^{-1}\cm^{-1} and an anomalous Hall angle of 6.66% occurs at a relatively low doping level of x=0.03x = 0.03. Based on the Tian-Ye-Jin (TYJ) scaling model, such a significant enhancement AHC is mainly dominated by the skew scattering. We speculated enhanced skew scattering between electrons and Mn originating from the strengthened spin-orbital coupling. Our finding provides important guidance for the design and development of transverse transport properties in topological Kagome materials.
In transmission X-ray microscopy (TXM) systems, the rotation of a scanned sample might be restricted to a limited angular range to avoid collision to other system parts or high attenuation at certain tilting angles. Image reconstruction from such limited angle data suffers from artifacts due to missing data. In this work, deep learning is applied to limited angle reconstruction in TXMs for the first time. With the challenge to obtain sufficient real data for training, training a deep neural network from synthetic data is investigated. Particularly, the U-Net, the state-of-the-art neural network in biomedical imaging, is trained from synthetic ellipsoid data and multi-category data to reduce artifacts in filtered back-projection (FBP) reconstruction images. The proposed method is evaluated on synthetic data and real scanned chlorella data in 100100^\circ limited angle tomography. For synthetic test data, the U-Net significantly reduces root-mean-square error (RMSE) from 2.55×1032.55 \times 10^{-3} {\mu}m1^{-1} in the FBP reconstruction to 1.21×1031.21 \times 10^{-3} {\mu}m1^{-1} in the U-Net reconstruction, and also improves structural similarity (SSIM) index from 0.625 to 0.920. With penalized weighted least square denoising of measured projections, the RMSE and SSIM are further improved to 1.16×1031.16 \times 10^{-3} {\mu}m1^{-1} and 0.932, respectively. For real test data, the proposed method remarkably improves the 3-D visualization of the subcellular structures in the chlorella cell, which indicates its important value for nano-scale imaging in biology, nanoscience and materials science.
The cross sections of 103Rh(n,gamma) and 103Rh(gamma,n) play a crucial role in the stellar nucleosynthesis, rhodium-based self-powered neutron detectors, and nuclear medicine. The cross sections of 103Rh(n,gamma) was measured by the time-of-flight(TOF) method from 1 eV to 1000 keV at the Back-n facility of the Chinese Spallation Neutron Source. In the resolved resonance region, the data reported multiple new resonance structures for the first time. And some discrepancies were observed, offering valuable insights into the differences between the evaluated libraries. Maxwellian-averaged cross sections (MACSs) were calculated within the temperature range of the s process nucleosynthesis model, based on the averaged cross sections in the unresolved resonance region. Meanwhile the cross sections of 103Rh(gamma,n) within the range of p process nucleosynthesis were measured using laser Compton scattering (LCS) gamma rays and a new neutron flat efficiency detector (FED) array at the Shanghai Laser Electron Gamma Source (SLEGS), Shanghai Synchrotron Radiation Facility (SSRF). Using an unfolding iteration method, 103Rh(gamma,n) data were obtained with uncertainty less than 5%, and the inconsistencies between the available experimental data and the evaluated libraries were discussed. This study provides a reliable benchmark for nuclear data evaluation and model optimization, and lays a solid foundation for Rh medical isotope applications and astrophysical research.
Plasma wakefield acceleration holds remarkable promise for future advanced accelerators. The design and optimization of plasma-based accelerators typically require particle-in-cell simulations, which can be computationally intensive and time consuming. In this study, we train a neural network model to obtain the on-axis longitudinal electric field distribution directly without conducting particle-in-cell simulations for designing a two-bunch plasma wakefield acceleration stage. By combining the neural network model with an advanced algorithm for achieving the minimal energy spread, the optimal normalized charge per unit length of a trailing beam leading to the optimal beam-loading can be quickly identified. This approach can reduce computation time from around 7.6 minutes in the case of using particle-in-cell simulations to under 0.1 seconds. Moreover, the longitudinal electric field distribution under the optimal beam-loading can be visually observed. Utilizing this model with the beam current profile also enables the direct extraction of design parameters under the optimal beam-loading, including the maximum decelerating electric field within the drive beam, the average accelerating electric field within the trailing beam and the transformer ratio. This model has the potential to significantly improve the efficiency of designing and optimizing the beam-driven plasma wakefield accelerators.
Polarization-analyzed small-angle neutron scattering (PASANS) is an advanced technique that enables the selective investigation of magnetic scattering phenomena in magnetic materials and distinguishes coherent scattering obscured by incoherent backgrounds, making it particularly valuable for cutting-edge research. The successful implementation of PASANS in China was achieved for the first time at the newly commissioned Very Small Angle Neutron Scattering (VSANS) instrument at the China Spallation Neutron Source (CSNS). This technique employs a combination of a double-V cavity supermirror polarizer and a radio frequency (RF) neutron spin flipper to manipulate the polarization of the incident neutrons. The scattered neutron polarization is stably analyzed by a specially designed in-situ\textit{in-situ} optical pumping 3^{3}He neutron spin filter, which covers a spatially symmetric scattering angle coverage of about 4.8 ^{\circ}. A comprehensive PASANS data reduction method, aimed at pulsed neutron beams, has been established and validated with a silver behenate powder sample, indicating a maximum momentum transfer coverage of approximately 0.25 Å 1^{-1}.
The magnetic ground state of geometrically frustrated antiferromagnet attracts great research interests due to the possibility to realize novel quantum magnetic state such as a quantum spin liquid. Here we present a comprehensive magnetic characterization of DyTa7_7O19_{19} with ideal two-dimensional triangular lattice. DyTa7_7O19_{19} exhibits cc-axis single-ion magnetic anisotropy. Although long-range magnetic order is not observed down to 100 mK under zero field, by applying a small magnetic field (\sim0.1 T), a magnetically ordered state with net magnetization of MsM_s/3 below TmT_m=0.14 K is identified (MsM_s denotes the saturated magnetization). We argue that this state is an up-up-down magnetic structure phase driven by the dipole-dipole interactions between Ising-like spins of Dy3+^{3+} in a two-dimensional triangular lattice, since its ordering temperature and temperature-field phase diagram can be well explained by the theoretical calculations based on dipolar interactions. DyTa7_7O19_{19} could be viewed as a rare material platform that realizing pure Ising-like dipolar interaction in a geometrically frustrated lattice.
Developing neutron spectrometers with higher counting efficiency has been an essential pursuit in neutron instrumentation. In this work, we present BOYA, a multiplexing cold neutron spectrometers designed and implemented at the China Advanced Research Reactor. Equipped with 34 angular analyzing channels spanning 119{\deg}, each containing 5 inelastic channels and 1 diffraction channel, BOYA enhances the measurement efficiency by two orders of magnitude over a traditional triple-axis spectrometer. To optimize both intensity and energy resolution, innovative double-column Rowland focusing analyzers have been developed. By filling the crystal gaps in the traditional Rowland focusing geometry, our design enhances the neutron beam coverage without introducing appreciable double-scattering. Our commissioning results on vanadium and MnWO4 have confirmed the success of the design, establishing BOYA as a successful multiplexing instrument for neutron spectroscopy.
We report the systematic synthesis, crystal structure, magnetization, and powder neutron diffraction of single crystalline and polycrystalline CaCo2_2TeO6_6 samples. CaCo2_2TeO6_6 crystallizes in an orthorhombic structure with PnmaPnma space group, featuring chains of edge-shared CoO6_6 octahedra arranged in a honeycomb pattern. Two antiferromagnetic transitions are observed at TTN1_{N1} = 14.4 K and TTN2_{N2} = 16.2 K, corresponding to two long-range magnetic orders with propagation vectors of k\bf{k}1_1 = (0, 0, 0) and k\bf{k}2_2 = (0.125, 0, 0.25), respectively. The ground state is determined as a canted up-up-down-down zigzag spin configuration along the cc axis, wherein the magnetic moments of Co1 and Co2 ions are 3.4(1) and 2.1(1)μ\muB_B, respectively. Successive spin-flop transitions appear with the increasing magnetic field applied along the easy axis (cc axis), accompanied by depression of the antiferromagnetic orders and enhancement of residual magnetic entropy. The field-induced spin-disordered state suggests that CaCo2_2TeO6_6 may be an ideal candidate for studying frustrated magnetism.
Lattice dynamics play a crucial role in understanding the physical mechanisms of cutting-edge energy materials. Many excellent energy materials have complex multiple-sublattice structures, with intricate lattice dynamics, and the underlying mechanisms are difficult to understand. Neutron scattering technologies, which are known for their high energy and momentum resolution, are powerful tools for simultaneously characterizing material structure and complex lattice dynamics. In recent years, neutron scattering techniques have made significant contributions to the study of energy materials, shedding light on their physical mechanisms. This review article details several neutron scattering techniques commonly used in energy material research, including neutron diffraction, total neutron scattering, quasi-elastic and inelastic neutron scattering. Then, some important research progress made in the field of energy materials in recent years using neutron scattering as the main characterization method is reviewed, including ultra-low lattice thermal conductivity in superionic thermoelectric materials, ion diffusion mechanism of solid-state electrolytes, plastic-crystalline phase transition and configuration entropy changes in barocaloric materials, lattice anharmonicity and charge transport in photovoltaic materials, and first-order magnetic-structural phase transition in magnetocaloric materials. In these complex energy conversion and storage materials, lattice dynamics do not work independently, and their functioning in macroscopic physical properties is always achieved through correlation or mutual coupling with other degrees of freedom, such as sublattices, charge, spin, etc. Through these typical examples, this review paper can provide a reference for further exploring and understanding the energy materials and lattice dynamics.
We present a combined X-ray and neutron diffraction, Raman spectroscopy, and 121Sb NMR studies of AgSbTe2, supported by first-principles calculations aiming to elucidate its crystal structure. While diffraction methods cannot unambiguously resolve the structure, Raman and NMR data, together with electric field gradient calculations, strongly support the rhombohedral R-3m phase. Moreover, the agreement between experimental and calculated Raman spectra further corroborates this result, resolving the 60-year sold debate about the exact crystal structure of the AgSbTe2 compound.
Pure borocarbides suffer from limited superconducting potential due to intrinsic structural instability, requiring transition/alkali metals as dual-functional stabilizers and dopants. Here, by combining high-throughput screening with anisotropic Migdal-Eliashberg (aME) theory, we identify dynamically stable borocarbides where high-Tc superconductivity predominately originates from E symmetry-selective electron-phonon coupling (EPC). The six distinct superconducting gaps emerge from a staircase distribution or uncoupling of EPC strength across each Fermi surface (FS) sheet, constituting a metal-free system with such high gap multiplicity. Crucially, dimensional reduction from bulk to surface strengthens E-symmetry EPC and enhances Tc from 32 K (3D bulk) to 75 K (2D surface), a result that highlights structural confinement as a key design strategy for observing high Tc. External strain further optimizes the competition between EPC strength and characteristic phonon frequency to achieve Tc > 90 K. This work reveals a systematic correlation between structural dimensionality and gap multiplicity and establishes borocarbide as a tunable platform to engineer both high-Tc and multi-gap superconductivity.
Jiangmen Underground Neutrino Observatory (JUNO) is a large-scale neutrino experiment with multiple physics goals including neutrino mass hierarchy, accurate measurement of neutrino oscillation parameters, neutrino detection from supernova, sun, and earth, etc. The Central Detector (CD) of JUNO using 20-kiloton Liquid Scintillator (LS) as target mass with 3% energy resolution at 1 MeV and low radioactive background. To achieve LS filling smoothly and detector running safely, JUNO's liquid Filling, Overflowing, and Circulating System (FOC) features a control system based on a Programmable Logic Controller and equipped with high-reliable sensors and actuators. This paper describes the design of the FOC automatic monitoring and control system including hardware and software. The control logic including Proportional-Integral-Derivative control, sequential control, and safety interlocks ensures precise regulation of key parameters such as flow rate, liquid level, and pressure. Test results demonstrate the FOC system can satisfy the requirement of JUNO detector filling and running operations.
Chiral phonons have attracted significant attention due to their potential applications in spintronics, superconductivity, and advanced materials, but their detection has predominantly relied on indirect photon-involved processes. Here, we propose inelastic neutron scattering (INS) as a direct and versatile approach for chiral phonon detection over a broad momentum-energy space. Leveraging INS sensitivity to phonon eigenmodes, we clearly distinguish linear, elliptical, and chiral phonons and determine phonon handedness through angle-resolved measurements. Using right-handed tellurium (Te) as a model system, we identify characteristic INS fingerprints that clearly separate chiral from linear phonons. Moreover, we show that INS can directly access phonon magnetic moments and the effective magnetic fields generated by chiral phonons, as evidenced by the pronounced mode splitting in CeF3_3. Collectively, these results position INS as a powerful platform for comprehensive investigations of chiral-phonon dynamics and their associated quantum phenomena.
Perovskite-type ternary nitrides with predicted exciting ferroelectricity and many other outstanding properties hold great promise to be an emerging class of advanced ferroelectrics for manufacturing diverse technologically important devices. However, such nitride ferroelectrics have not yet been experimentally identified, mainly due to the challenging sample synthesis by traditional methods at ambient pressure. Here we report the successful high-pressure synthesis of a high-quality ferroelectric nitride perovskite of CeTaN3-{\delta} with nitrogen deficiency, adopting an orthorhombic Pmn21 polar structure. This material is electrically insulating and exhibits switchable and robust electric polarization for producing ferroelectricity. Furthermore, a number of other extraordinary properties are also revealed in this nitride such as excellent mechanical properties and chemical inertness, which would make it practically useful for many device-relevant applications and fundamentally important for the study of condensed-matter physics.
Angle-differential cross sections for neutron-induced α\alpha production in carbon were determined at thirty discrete neutron energy levels ranging from 6.2 to 76 MeV at the Back-n white neutron source of the China Spallation Neutron Source. Utilizing the ΔEE{\Delta}E-E telescopes within the Light-charged Particle Detector Array spanning angular measurements from 24.5°to 155.5° in the laboratory frame, the 12C(n,α)x^{12}C(n,\alpha)x reaction cross sections were obtained. These experimental findings exhibit a strong concordance with prior results and have been benchmarked against theoretical estimates from codes such as TALYS, Geant4, and assessments from the ENDF/B-VIII.0 database. Remarkably, distinct resonance-like features were observed at neutron energies of 13.7, 22.4, 29.5, and 61.8 MeV, marking their first-time identification in the this http URL, a comparative analysis involving the theoretical Distorted Wave Born Approximation was conducted.
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