We prove that strictly stationary spacetimes cannot contain closed trapped nor marginally trapped surfaces. The result is purely geometric and holds in arbitrary dimension. Other results concerning the interplay between (generalized) symmetries and trapped submanifolds are also presented.

Hysteretic gate responses of two-dimensional material heterostructures serve as sensitive probes of the underlying electronic states and hold significant promise for the development of novel nanoelectronic devices. Here we identify a new mechanism of hysteretic behavior in graphene/$h$BN/$\alpha$-$\mathrm{RuCl_3}$ charge transfer field effect devices. The hysteresis loop exhibits a sharp onset under low temperatures and evolves symmetrically relative to the charge transfer equilibrium. Unlike conventional flash memory devices, the charge transfer heterostructure features a transparent tunneling barrier and its hysteretic gate response is induced by the dynamic tuning of interfacial dipoles originating from quantum exchange interactions. The system acts effectively as a ferroelectric and gives rise to remarkable tunability of the hysteretic gate response under external electrical bias. Our work unveils a novel mechanism for engineering hysteretic behaviors via dynamic interfacial quantum dipoles.

We propose a macroscopic theory of optical phonons, Fr{ö}hlich polarons, and exciton-polarons in two-dimensional (2D) polar crystalline monolayers. Our theory extends the classical macroscopic formulation of the electron-phonon problem in three-dimensional (3D) polar crystals to the new generation of 2D materials. Similarly to the 3D case, in our approach, the effective electron-phonon Hamiltonian is parametrized solely in terms of macroscopic experimentally accessible quantities -- 2D polarizabilities of the monolayer at low and high frequencies. We derive the dispersion of long wave length longitudinal optical (LO) phonons, which can be viewed as a 2D form of the Lyddane-Sachs-Teller relation, and study the formation of 2D Fr{ö}hlich polarons by adopting the intermediate coupling approximation. Finally, we apply this approach to excitons in polar 2D crystals and derive an effective potential of the electron-hole interaction dressed by LO phonons. Due to a specific dispersion of LO phonons, polarons and exciton-polarons in 2D materials exhibit unique features not found in their 3D counterparts. As an illustration, the polaron and exciton-polaron binding energies are computed for a representative set of 2D polar crystals, demonstrating the interplay between dimensionality, polarizability of materials, and electron-phonon coupling.

It is argued that ultracold quantum degenerate gas of ytterbium $^{173}$Yb atoms having nuclear spin $I = 5/2$ exhibits an enlarged SU$(6)$ symmetry. Within the Landau Fermi liquid theory, stability criteria against Fermi liquid (Pomeranchuk) instabilities in the spin channel are considered. Focusing on the SU$(n > 2)$ generalizations of ferromagnetism, it is shown within mean-field theory that the transition from the paramagnet to the itinerant ferromagnet is generically first order. On symmetry grounds, general SU$(n)$ itinerant ferromagnetic ground states and their topological excitations are also discussed. These SU$(n > 2)$ ferromagnets can become stable by increasing the scattering length using optical methods or in an optical lattice. However, in an optical lattice at current experimental temperatures, Mott states with different filling are expected to coexist in the same trap, as obtained from a calculation based on the SU$(6)$ Hubbard model.

A very simple criterion to ascertain if (D-2)-surfaces are trapped in arbitrary D-dimensional Lorentzian manifolds is given. The result is purely geometric, independent of the particular gravitational theory, of any field equations or of any other conditions. Many physical applications arise, a few shown here: a definition of general horizon, which reduces to the standard one in black holes/rings and other known cases; the classification of solutions with a (D-2)-dimensional abelian group of motions and the invariance of the trapping under simple dimensional reductions of the Kaluza-Klein/string/M-theory type. Finally, a stronger result involving closed trapped surfaces is presented. It provides in particular a simple sufficient condition for their absence.

The cross-dock door design problem consists of deciding the strip and stack doors and nominal capacity of an entity under uncertainty. Inbound commodity flow from origin nodes is assigned to the strip doors, it is consolidated in the entity, and the outbound flow is assigned to the stack ones for being delivered to destination nodes, at a minimum cost. The problem combines three highly computational difficulties, namely, NP-hard combinatorics, uncertainty in the main parameters and their probability distribution. Distributionally robust optimization is considered to deal with these uncertainties. Its related two-stage mixed binary quadratic model is presented for cross-dock problem-solving; the first stage decisions are related to the design of the entity; the second stage ones are related to the assignment of the commodity flow to the doors in a finite set of scenarios for the ambiguity set members. The goal is to minimize the highest total cost in the ambiguity set, subject to the constraint system for each of those members and the stochastic dominance risk averse functional. As far as we know, the challenging problem that results has not been addressed before, although its application field is a very broad one. Given the problem-solving difficulty, a scenario cluster decomposition and a min-max based matheuristic are proposed for obtaining lower and upper bounds, respectively. A computational study validates the proposal; it overperformances the straightforward use of the state-of-the-art solvers Cplex and Gurobi.

We provide an insight into the origin of the phenomena reported 40 years ago by Kerker, Wang and Giles (Journal of the Optical Society of America, 73, 6, pp. 765-767, (1983)). We show that the impedance and refractive index matching conditions, discussed in Sections II and IV of the seminal paper, are intimately related with space-time symmetries. We derive our results starting from the theory of representations of the Poincaré group, as it is the theory on which one of the most elemental descriptions of electromagnetic waves is based. We show that fundamental features of electromagnetic waves in material environments can be derived from group theoretical arguments. In particular, we identify the Casimir invariants of $P_{\scriptscriptstyle{3,1}}$ subgroup as the magnitudes which describe the nature of monochromatic electromagnetic waves propagating in matter. Finally, we show that the emergence of the Kerker phenomena is associated with the conservation of such Casimir invariants in piecewise homogeneous media.

We examine the recently proposed technique of adding boundary counterterms to the gravitational action for spacetimes which are locally asymptotic to anti-de Sitter. In particular, we explicitly identify higher order counterterms, which allow us to consider spacetimes of dimensions d<=7. As the counterterms eliminate the need of ``background subtraction'' in calculating the action, we apply this technique to study examples where the appropriate background was ambiguous or unknown: topological black holes, Taub-NUT-AdS and Taub-Bolt-AdS. We also identify certain cases where the covariant counterterms fail to render the action finite, and we comment on the dual field theory interpretation of this result. In some examples, the case of vanishing cosmological constant may be recovered in a limit, which allows us to check results and resolve ambiguities in certain asymptotically flat spacetime computations in the literature.

The Vaidya solution describes the gravitational collapse of a finite shell of incoherent radiation falling into flat spacetime and giving rise to a Schwarzschild black hole. There has been a question whether closed trapped surfaces can extend into the flat region (whereas closed outer trapped surfaces certainly can). For the special case of self-similar collapse we show that the answer is yes, if and only if the mass function rises fast enough.

The excitonic insulator is an electronically-driven phase of matter that emerges upon the spontaneous formation and Bose condensation of excitons. Detecting this exotic order in candidate materials is a subject of paramount importance, as the size of the excitonic gap in the band structure establishes the potential of this collective state for superfluid energy transport. However, the identification of this phase in real solids is hindered by the coexistence of a structural order parameter with the same symmetry as the excitonic order. Only a few materials are currently believed to host a dominant excitonic phase, Ta$_2$NiSe$_5$ being the most promising. Here, we test this scenario by using an ultrashort laser pulse to quench the broken-symmetry phase of this transition metal chalcogenide. Tracking the dynamics of the material's electronic and crystal structure after light excitation reveals surprising spectroscopic fingerprints that are only compatible with a primary order parameter of phononic nature. We rationalize our findings through state-of-the-art calculations, confirming that the structural order accounts for most of the electronic gap opening. Not only do our results uncover the long-sought mechanism driving the phase transition of Ta$_2$NiSe$_5$, but they also conclusively rule out any substantial excitonic character in this instability.

The inherently weak nonlinear optical response of bulk materials remains a fundamental limitation in advancing photonic technologies. Nanophotonics addresses this challenge by tailoring the size and morphology of nanostructures to manipulate the optical near field, thus modulating the nonlinear response. Here, we explore a complementary strategy based on engineering the electronic band structure in the mesoscopic regime to enhance optical nonlinearities. Specifically, we demonstrate an increase in second-harmonic generation (SHG) from crystalline silver films as their thickness is reduced down to just a few atomic monolayers. Operating at the boundary between bulk and two-dimensional systems, these ultra-thin films exhibit a pronounced enhancement of SHG with decreasing thickness. This enhancement stems from quantum confinement effects that modify the interaction between electronic states and incident light, which we explain based on quantum-mechanical calculation. Our atomically-thin crystalline silver films provide a new means to overcome the small interaction volumes inherent to nanophotonic platforms, enabling efficient nanoscale nonlinear optics with potential applications in photonics, sensing, and quantum technologies.

We present a numerical implementation, based on Wannier interpolation, of a Kubo-Greenwood formalism for computing the spatially dispersive optical conductivity in crystals at first order in the wave vector of light. This approach is more efficient than direct $\textit{ab initio}$ methods because, with less computational cost, it allows for a much finer sampling of reciprocal space, resulting in better resolved spectra. Moreover, Wannier interpolation avoids errors arising from truncation of the sums over conduction bands when evaluating the spatially dispersive optical matrix elements. We validate our method by computing the optical activity spectrum of selected crystals, both polar (GaN) and chiral (trigonal Te, trigonal Se, and $\alpha$-quartz), and comparing with existing literature.

The calculation of quantum-geometric properties of Bloch electrons -- Berry curvature, quantum metric, orbital magnetic moment and effective mass -- was implemented in a pseudopotential plane-wave code. The starting point was the first derivative of the periodic part of the wavefunction psi_k with respect to the wavevector k. This was evaluated with perturbation theory by solving a Sternheimer equation. Comparison of effective masses obtained from perturbation theory for silicon and gallium arsenide with carefully-converged numerical second derivatives of band energies confirms the high precision of the method. Calculations of quantum-geometric quantities for gapped graphene were performed by adding a bespoke symmetry-breaking potential to first-principles graphene. As the two bands near the opened gap are reasonably isolated, the results could be compared with those obtained from an analytical two-band model, allowing to assess the strengths and limitations of such widely-used models. The final application was trigonal tellurium, where quantum-geometric quantities flip sign with chirality.

We discuss Dirichlet instanton effects on type-IIB string Thermodynamics. We review some general properties of dilute D-instanton gases and use the low-energy supergravity solutions to define the normalization of the instanton measure, as well as the effects of long-range interactions. Thermal singularities in the single-instanton sector are due to tachyonic winding modes of Dirichlet open strings. Purely bosonic D-instantons induce in this way hard infrared singularities that ruin the weak-coupling expansion in the microcanonical ensemble. However, type-IIB D-instantons, give smooth contributions at the Hagedorn temperature, and the induced mass and coupling of the axion field are insufficient to change the first-order character of the phase transition in the mean field approximation.

We present a systematic study of bound relations between different electronic properties of magnetic crystals: electron density, effective mass, orbital magnetization, localization length, Chern invariant, and electric susceptibility. All relations are satisfied for a group of low-lying bands, while some remain valid for upper bands. New results include a lower bound on the electric susceptibility of Chern insulators, and an upper bound on the sum-rule part of the orbital magnetization. In addition, bounds involving the Chern invariant are generalized from two dimensions (Chern number) to three (Chern vector). Bound relations are established for metals as well as insulators, and are illustrated for model systems. The manner in which they approach saturation in a model Chern insulator with tunable flat bands is analyzed in terms of the optical absorption spectrum.

We present a systematic study of bound relations between different electronic properties of magnetic crystals: electron density, effective mass, orbital magnetization, localization length, Chern invariant, and electric susceptibility. All relations are satisfied for a group of low-lying bands, while some remain valid for upper bands. New results include a lower bound on the electric susceptibility of Chern insulators, and an upper bound on the sum-rule part of the orbital magnetization. In addition, bounds involving the Chern invariant are generalized from two dimensions (Chern number) to three (Chern vector). Bound relations are established for metals as well as insulators, and are illustrated for model systems. The manner in which they approach saturation in a model Chern insulator with tunable flat bands is analyzed in terms of the optical absorption spectrum.

Twisted van der Waals heterostructures have latterly received prominent attention for their many remarkable experimental properties, and the promise that they hold for realising elusive states of matter in the laboratory. We propose that these systems can, in fact, be used as a robust quantum simulation platform that enables the study of strongly correlated physics and topology in quantum materials. Among the features that make these materials a versatile toolbox are the tunability of their properties through readily accessible external parameters such as gating, straining, packing and twist angle; the feasibility to realize and control a large number of fundamental many-body quantum models relevant in the field of condensed-matter physics; and finally, the availability of experimental readout protocols that directly map their rich phase diagrams in and out of equilibrium. This general framework makes it possible to robustly realize and functionalize new phases of matter in a modular fashion, thus broadening the landscape of accessible physics and holding promise for future technological applications.

We identify a distinct transverse collective excitation, which we name the "curron", arising from current-current interactions in a driven quantum metal. Unlike plasmons, which involve longitudinal charge oscillations, currons are transverse current-density oscillations resulting from the interplay between the vector potential generated by the current and the external driving field. We demonstrate the emergence of this excitation in sodium metal by solving the Kadanoff-Baym equations on a complex time contour within the non-equilibrium two-time (TT) $GW$ formalism, marking, to our knowledge, the first TT-$GW$ calculation on a realistic material. We further show that two-time quantum memory effects leave measurable signatures: a pump-induced elevation in the baseline of the current-to-field response, potentially observable in polarization- and momentum-resolved conductivity experiments. By extracting effective resistive and memory coefficients from the TT-$GW$ dynamics, we introduce a generalized d'Alembert wave equation that captures the many-body damping and retardation inherent to driven quantum systems. These results establish current-current response functions as a platform to harness qualitatively new collective dynamics in correlated matter, opening new avenues for probing light-matter interactions beyond charge-density dynamics.

Data show that the presence of women in quantum science is affected by a number of detriments and their percentage decreases even further for higher positions. Beyond data, from our shared personal experiences as female tenured quantum physics professors, we believe that the current model of scientific leadership, funding, and authority fails to represent many of us. It is time for a real change that calls for a different kind of force and for the participation of everyone. Women for quantum calls for a joint effort and aims with this initiative to contribute to such a transformation.

This Thesis delves into the development and implementation of quantum algorithms using the digital-analog quantum computing (DAQC) paradigm. It provides a comparative analysis of the performance of DAQC versus traditional digital approaches, particularly in the presence of noise sources from current noisy intermediate-scale quantum (NISQ) devices. The DAQC paradigm combines the strengths of digital and analog quantum computing, offering greater efficiency and precision for implementing quantum algorithms on real hardware. The Thesis focuses on the comparison of four relevant quantum algorithms using digital and digital-analog approaches, and the results show significant advantages in favor of the latter. Furthermore, the Thesis investigates the cross-resonance effect to achieve efficient and high-precision Hamiltonian simulations. The findings indicate that the digital-analog paradigm is promising for practical quantum computing applications. Its ability to deliver greater efficiency and accuracy in implementing quantum algorithms on real hardware is a significant advantage over traditional digital approaches.