National Synchrotron Radiation Research Center
Antiferromagnets (AFMs) exhibit spin arrangements with no net magnetization, positioning them as promising candidates for spintronics applications. While electrical manipulation of the single-crystal AFMs, composed of periodic spin configurations, is achieved recently, it remains a daunting challenge to characterize and to manipulate polycrystalline AFMs. Utilizing statistical analysis in data science, we demonstrate that polycrystalline AFMs can be described using a real, symmetric, positive semi-definite, rank-two tensor, which we term the Neel tensor. This tensor introduces a unique spin torque, diverging from the conventional field-like and Slonczewski torques in spintronics devices. Remarkably, Neel tensors can be trained to retain a specific orientation, functioning as a form of working memory. This attribute enables zero-field spin-orbit-torque switching in trilayer devices featuring a heavy-metal/ferromagnet/AFM structure and is also consistent with the X-ray magnetic linear dichroism measurements. Our findings uncover hidden statistical patterns in polycrystalline AFMs and establishes the presence of Neel tensor torque, highlighting its potential to drive future spintronics innovations.
We present the Quantum Kernel-Based Long short-memory (QK-LSTM) network, which integrates quantum kernel methods into classical LSTM architectures to enhance predictive accuracy and computational efficiency in climate time-series forecasting tasks, such as Air Quality Index (AQI) prediction. By embedding classical inputs into high-dimensional quantum feature spaces, QK-LSTM captures intricate nonlinear dependencies and temporal dynamics with fewer trainable parameters. Leveraging quantum kernel methods allows for efficient computation of inner products in quantum spaces, addressing the computational challenges faced by classical models and variational quantum circuit-based models. Designed for the Noisy Intermediate-Scale Quantum (NISQ) era, QK-LSTM supports scalable hybrid quantum-classical implementations. Experimental results demonstrate that QK-LSTM outperforms classical LSTM networks in AQI forecasting, showcasing its potential for environmental monitoring and resource-constrained scenarios, while highlighting the broader applicability of quantum-enhanced machine learning frameworks in tackling large-scale, high-dimensional climate datasets.
We examine the bulk electronic structure of Nd3Ni2O7 using Ni 2p core-level hard x-ray photoemission spectroscopy combined with density functional theory + dynamical mean-field theory. Our results reveal a large deviation of the Ni 3d occupation from the formal Ni2.5+ valency, highlighting the importance of the charge-transfer from oxygen ligands. We find that the dominant d8 configuration is accompanied by nearly equal contributions from d7 and d9 states, exhibiting an unusual valence state among Ni-based oxides. Finally, we discuss the Ni dx2-y2 and dz2 orbital-dependent hybridization, correlation and local spin dynamics.
In the 1960s, Lifshitz et al. predicted that quantum fluctuations can change the van der Waals (vdW) interactions from attraction to repulsion. However, the vdW repulsion, or its long-range counterpart - the Casimir repulsion, has only been demonstrated in liquid. Here we show that the atomic thickness and birefringent nature of two-dimensional materials make them a versatile medium to tailor the Lifshitz-vdW interactions. Based on our theoretical prediction, we present direct force measurement of vdW repulsion on 2D material surfaces without liquid immersion and demonstrate their substantial influence on epitaxial properties. For example, heteroepitaxy of gold on a sheet of freestanding graphene leads to the growth of ultrathin platelets, owing to the vdW repulsion-induced ultrafast diffusion of gold clusters. The creation of repulsive force in nanoscale proximity offers technological opportunities such as single-molecule actuation and atomic assembly.
The integration of quantum computing into classical machine learning architectures has emerged as a promising approach to enhance model efficiency and computational capacity. In this work, we introduce the Quantum Kernel-Based Long Short-Term Memory (QK-LSTM) network, which utilizes quantum kernel functions within the classical LSTM framework to capture complex, non-linear patterns in sequential data. By embedding input data into a high-dimensional quantum feature space, the QK-LSTM model reduces the reliance on large parameter sets, achieving effective compression while maintaining accuracy in sequence modeling tasks. This quantum-enhanced architecture demonstrates efficient convergence, robust loss minimization, and model compactness, making it suitable for deployment in edge computing environments and resource-limited quantum devices (especially in the NISQ era). Benchmark comparisons reveal that QK-LSTM achieves performance on par with classical LSTM models, yet with fewer parameters, underscoring its potential to advance quantum machine learning applications in natural language processing and other domains requiring efficient temporal data processing.
High-Tc_c superconductivity has recently been discovered in Ruddlesden-Popper phase nickelates under pressure, where the low-energy electronic structure is dominated by Ni dx2y2d_{x^2 - y^2} and dz2d_{z^2} orbitals. However, the respective roles of these orbitals in superconductivity remain unclear. Here, by combining X-ray absorption, electron energy loss spectroscopy, and density functional theory calculations on La4_{4}Ni3_{3}O10_{10} single crystals, we identify ligand holes in the px,yp_{x,y} orbitals of planar oxygen and the pzp_z orbitals of apical oxygen, which hybridize with the Ni dx2y2d_{x^2-y^2} and dz2d_{z^2} orbitals, respectively. These ligand holes enable orbital-selective O K-edge resonant inelastic X-ray scattering (RIXS) study, which reveals that dx2y2d_{x^2-y^2} states dominate the low-energy charge excitations and are more itinerant. We also observe a \sim0.1 eV bimagnon through RIXS and Raman spectroscopy, which leads to an interlayer superexchange interaction Jz_z of \sim50 meV. Our results reveal distinct contributions of Ni dx2y2d_{x^2-y^2} and dz2d_{z^2} orbitals to the electronic and magnetic structure and provide direct experimental insights to understand the RP-phase nickelate superconductors.
We report on the study of the magnetic excitations of Mott insulator La2CuO4 by using resonant inelastic x-ray scattering (RIXS) and cluster calculations within the framework of exact diagonalization. Our results demonstrate experimentally that the bimagnon excitation in Cu L-edge RIXS is enhanced if the incident x-ray energy is slightly above the absorption edge. Through incident-energy-dependent momentum-resolved RIXS, we investigated the excitation of the bimagnon with predominantly A1 symmetry. The bimagnons of La2CuO4 exhibit a nearly flat dispersion with momentum along the Cu-O bond direction. This observation agrees with the bimagnon dispersion from the calculations on a single-band Hubbard model rather than a Heisenberg model with only the nearest neighbor exchange interaction. This means that the effect of the higher-order spin couplings such as the cyclic or ring exchange interactions caused by the coherent motion of electrons beyond nearest-neighbor sites is important for understanding the bimagnon dynamics of cuprates.
We demonstrate that a multi-k\mathbf{k} incommensurate magnetic state in the Weyl semimetal CeAlGe gives rise to singular angular magnetoresistance (SAMR), an electrical-transport signature that detects the magnetic-field direction with exceptional precision. In contrast, the sister compound CeAlSi shows neither multi-k\mathbf{k} order nor SAMR. Both phenomena emerge upon 57%\sim57\% Ge substitution in CeAlSi1x_{1-x}Gex_x and coincide with electronic-structure changes that soften the single-ion in-plane anisotropy and enhance Weyl-mediated magnetic interactions. These results reveal a direct connection between band topology, electronic transport, and collective magnetism in Weyl semimetals.
Present work investigates the magnetic and electronic structure of MgO/Fe/MgO/Fe/Co/Au multilayer stack grown on Si(100) substrates by electron beam evaporation method. X-ray diffraction study depicts polycrystalline nature of the multilayers. Results obtained from vibrating sample magnetometry (VSM) and near-edge X-ray absorption fine structure spectra (NEXAFS) at Fe & Co L- and Mg & O K-edges are applied to understand the magnetic and electronic properties of this stack and its interface properties. While the spectral features of Fe L-edge spectrum recorded by surface sensitive total electron yield (TEY) mode shows the formation of FeOx at the Fe/MgO interface, the bulk sensitive total fluorescence yield (TFY), shows Fe in metallic nature. Co L-edge spectrum reveals the presence of metallic nature of cobalt in both TEY and TFY modes. Above results are well correlated with X-ray reflectometry.
Transition-metal ions with 5d25d^2 electronic configuration in a cubic crystal field are prone to have a vanishing dipolar magnetic moment but finite higher-order multipolar moments, and they are expected to exhibit exotic physical properties. Through an investigation using resonant inelastic X-ray spectroscopy (RIXS), Raman spectroscopy, and theoretical ligand-field (LF) multiplet and abinitioab initio calculations, we fully characterized the local electronic structure of Ba2_2CaOsO6_6, particularly, the crystal-field symmetry of the 5d2d^2 electrons in this anomalous material. The low-energy multiplet excitations from RIXS at the oxygen KK edge and Raman-active phonons both show no splitting. These findings are consistent with the ground state of Os ions dominated by magnetic octupoles. Obtained parameters pave the way for further realistic microscopic studies of this highly unusual class of materials, advancing our understanding of spin-orbit physics in systems with higher-order multipoles.
The layered 3d3d transition metal dichalcogenides (TMDs) CoTe2_2 and NiTe2_2 are topological Dirac Type-II metals. Their dd-bands do not exhibit the expected correlation-induced band narrowing seen in CoO and NiO. We address this conundrum by quantifying the on-site Coulomb energy UddU_{dd} via single-particle partial density of states and the two-hole correlation satellite using valence band resonant photoemission spectroscopy (PES), and obtain UddU_{dd} = 3.0 eV/3.7 eV for CoTe2_2/NiTe2_2. Charge-transfer (CT) cluster model simulations of the measured core-level PES and x-ray absorption spectra of CoTe2_2 and CoO validate their contrasting electronic parameters:UddU_{dd} and CT energy Δ\Delta are (3.0 eV, -2.0 eV) for CoTe2_2, and (5.0 eV, 4.0 eV) for CoO, respectively. The dd-pp hybridization strength TegT_{eg} for CoTe2_2<CoO, and indicates that the reduced UddU_{dd} in CoTe2_2 is not due to TegT_{eg}. The increase in dnd^n-count\sim1 by CT from ligand to Co site in CoTe2_2 is due to a negative-Δ\Delta and reduced UddU_{dd}. Yet, only because UddU_{dd}>Δ\big|\Delta\big|, CoTe2_{2} becomes a topological metal with pp\rightarrowp{p} type lowest energy excitations. Similarly, we obtain a negative-Δ\Delta and reduced UddU_{dd} in NiTe2_2 compared to NiO. The study reveals the nexus between negative-Δ\Delta and reduced UddU_{dd} required for setting up the electronic structure framework for achieving topological behavior via band inversion in correlated metals.
Localized 5d25d^2 electrons in a cubic crystal field possess multipoles such as electric quadrupoles and magnetic octupoles. We studied the cubic double perovskite Ba2_2CaOsO6_6 containing the Os6+^{6+} (5d25d^2) ions, which exhibits a phase transition to a `hidden order' below TT^* \sim 50 K, by X-ray absorption spectroscopy (XAS) and X-ray magnetic circular dichroism (XMCD) at the Os L2,3L_{2,3} edge. The cubic ligand-field splitting between the t2gt_{2g} and ege_g levels of Os 5d5d was deduced by XAS to be \sim4 eV. The temperature dependence of the XMCD spectra was consistent with a \sim18 meV residual cubic splitting of the lowest Jeff=J_{\rm eff} = 2 multiplet state into the non-Kramers EgE_g doublet ground state and the T2gT_{2g} triplet excited state. Ligand-field (LF) multiplet calculation under fictitious strong magnetic fields indicated that the exchange interaction between nearest-neighbor octupoles should be as strong as \sim1.5 meV if a ferro-octupole order is stabilized in the `hidden-ordered' state, consistent with the exchange interaction of \sim1 meV previously predicted theoretically using model and density functional theory calculations.
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We search for gravitational-wave signals associated with gamma-ray bursts detected by the Fermi and Swift satellites during the second half of the third observing run of Advanced LIGO and Advanced Virgo (1 November 2019 15:00 UTC-27 March 2020 17:00 UTC).We conduct two independent searches: a generic gravitational-wave transients search to analyze 86 gamma-ray bursts and an analysis to target binary mergers with at least one neutron star as short gamma-ray burst progenitors for 17 events. We find no significant evidence for gravitational-wave signals associated with any of these gamma-ray bursts. A weighted binomial test of the combined results finds no evidence for sub-threshold gravitational wave signals associated with this GRB ensemble either. We use several source types and signal morphologies during the searches, resulting in lower bounds on the estimated distance to each gamma-ray burst. Finally, we constrain the population of low luminosity short gamma-ray bursts using results from the first to the third observing runs of Advanced LIGO and Advanced Virgo. The resulting population is in accordance with the local binary neutron star merger rate.
Present work investigates the magnetic and electronic structure of MgO/Fe/MgO/Fe/Co/Au multilayer stack grown on Si(100) substrates by electron beam evaporation method. X-ray diffraction study depicts polycrystalline nature of the multilayers. Results obtained from vibrating sample magnetometry (VSM) and near-edge X-ray absorption fine structure spectra (NEXAFS) at Fe & Co L- and Mg & O K-edges are applied to understand the magnetic and electronic properties of this stack and its interface properties. While the spectral features of Fe L-edge spectrum recorded by surface sensitive total electron yield (TEY) mode shows the formation of FeOx at the Fe/MgO interface, the bulk sensitive total fluorescence yield (TFY), shows Fe in metallic nature. Co L-edge spectrum reveals the presence of metallic nature of cobalt in both TEY and TFY modes. Above results are well correlated with X-ray reflectometry.
We report on the study of the magnetic excitations of Mott insulator La2CuO4 by using resonant inelastic x-ray scattering (RIXS) and cluster calculations within the framework of exact diagonalization. Our results demonstrate experimentally that the bimagnon excitation in Cu L-edge RIXS is enhanced if the incident x-ray energy is slightly above the absorption edge. Through incident-energy-dependent momentum-resolved RIXS, we investigated the excitation of the bimagnon with predominantly A1 symmetry. The bimagnons of La2CuO4 exhibit a nearly flat dispersion with momentum along the Cu-O bond direction. This observation agrees with the bimagnon dispersion from the calculations on a single-band Hubbard model rather than a Heisenberg model with only the nearest neighbor exchange interaction. This means that the effect of the higher-order spin couplings such as the cyclic or ring exchange interactions caused by the coherent motion of electrons beyond nearest-neighbor sites is important for understanding the bimagnon dynamics of cuprates.
X-ray circular dichroism, arising from the contrast in X-ray absorption between opposite photon helicities, serves as a spectroscopic tool to measure the magnetization of ferromagnetic materials and identify the handedness of chiral crystals. Antiferromagnets with crystallographic chirality typically lack X-ray magnetic circular dichroism because of time-reversal symmetry, yet exhibit weak X-ray natural circular dichroism. Here, we report the observation of giant natural circular dichroism in the Ni L3L_3-edge X-ray absorption of Ni3_3TeO6_6, a polar and chiral antiferromagnet with effective time-reversal symmetry. To unravel this intriguing phenomenon, we propose a phenomenological model that classifies the movement of photons in a chiral crystal within the same symmetry class as that of a magnetic field. The coupling of X-ray polarization with the induced magnetization yields giant X-ray natural circular dichroism, revealing the altermagnetism of Ni3_3TeO6_6. Our findings provide evidence for the interplay between magnetism and crystal chirality in natural optical activity. Additionally, we establish the first example of a new class of magnetic materials exhibiting circular dichroism with time-reversal symmetry.
High-entropy-alloy (HEA) superconductors are a new class of disordered superconductors. In this study, we investigate the robustness of superconducting states in HEA-type metal telluride (MTe; M = Ag, In, Sn, Pb, Bi) under high pressure. PbTe exhibits a structural transition from a NaCl-type to an orthorhombic Pnma structure at low pressures, and further transitions to a CsCl-type structure at high pressures. When the superconductivity of the CsCl-type PbTe is observed, it is found that its superconducting transition temperature (Tc) decreases with pressure. However, in the HEA-type AgInSnPbBiTe5, Tc is almost independent of pressure, for pressures ranging from 13.0 to 35.1 GPa. This trend is quite similar to that observed in an HEA superconductor (TaNb)0.67(HfZrTi)0.33, which shows that the robustness of superconductivity to external pressure is a universal feature in HEA-type superconductors. To clarify the effects of the modification of the configurational entropy of mixing on the crystal structure, superconducting states, and electronic structure of MTe, electrical resistance measurements, synchrotron X-ray diffraction, and synchrotron X-ray absorption spectroscopy with partial fluorescence mode (PFY-XAS) for three MTe polycrystalline samples of PbTe, AgPbBiTe3, and AgInSnPbBiTe5 with different configurational entropies of mixing at the M site were performed.
The differential cross sections and decay angular distributions for coherent ϕ\phi-meson photoproduction from helium-4 have been measured for the first time at forward angles with linearly polarized photons in the energy range Eγ=1.685-2.385 GeVE_{\gamma} = \text{1.685-2.385 GeV}. Thanks to the target with spin-parity JP=0+J^{P} = 0^{+}, unnatural-parity exchanges are prohibited, and thus natural-parity exchanges can be investigated clearly. The decay asymmetry with respect to photon polarization is shown to be very close to the maximal value. This ensures the dominance (>94%> 94\%) of natural-parity exchanges in this reaction. To evaluate the contribution from natural-parity exchanges to the forward cross section (θ=0\theta = 0^\circ) for the $\gamma p \rightarrow \phi p$ reaction near the threshold, the energy dependence of the forward cross section (θ=0\theta = 0^\circ) for the $\gamma {^{4}\text{He}} \rightarrow \phi {^{4}\text{He}}reactionwasanalyzed.Thecomparisonto reaction was analyzed. The comparison to \gamma p \rightarrow \phi p$ data suggests that enhancement of the forward cross section arising from natural-parity exchanges, and/or destructive interference between natural-parity and unnatural-parity exchanges is needed in the $\gamma p \rightarrow \phi p$ reaction near the threshold.
We present an efficient tensor-network-based approach for simulating large-scale quantum circuits, demonstrated using Quantum Support Vector Machines (QSVMs). Our method effectively reduces exponential runtime growth to near-quadratic scaling with respect to the number of qubits in practical scenarios. Traditional state-vector simulations become computationally infeasible beyond approximately 50 qubits; in contrast, our simulator successfully handles QSVMs with up to 784 qubits, completing simulations within seconds on a single high-performance GPU. Furthermore, by employing the Message Passing Interface (MPI) in multi-GPU environments, the approach shows strong linear scalability, reducing computation time as dataset size increases. We validate the framework on the MNIST and Fashion MNIST datasets, achieving successful multiclass classification and emphasizing the potential of QSVMs for high-dimensional data analysis. By integrating tensor-network techniques with high-performance computing resources, this work demonstrates both the feasibility and scalability of large-qubit quantum machine learning models, providing a valuable validation tool in the emerging Quantum-HPC ecosystem.
We have performed angle-resolved photoemission spectroscopy on transition-metal dichalcogenide 1TT-HfTe2_2 to elucidate the evolution of electronic states upon potassium (K) deposition. In pristine HfTe2_2, an in-plane hole pocket and electron pockets are observed at the Brillouin-zone center and corner, respectively, indicating the semimetallic nature of bulk HfTe2_2, with dispersion perpendicular to the plane. In contrast, the band structure of heavily K-dosed HfTe2_2 is obviously different from that of bulk, and resembles the band structure calculated for monolayer HfTe2_2. It was also observed that lightly K-dosed HfTe2_2 is characterized by quantized bands originating from bilayer and trilayer HfTe2_2, indicative of staging. The results suggest that the dimensionality-crossover from 3D (dimensional) to 2D electronic states due to systematic K intercalation takes place via staging in a single sample. The study provides a new strategy for controlling the dimensionality and functionality of novel quantum materials.
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