The
S=1/2 antiferromagnetic Heisenberg chain is a paradigmatic quantum system hosting exotic excitations such as spinons and solitons, and forming random singlet state in the presence of quenched disorder. Realizing and distinguishing these excitations in a single material remains a significant challenge. Using nuclear magnetic resonance (NMR) on a high-quality single crystal of copper benzoate, we identify and characterize all three excitation types by tuning the magnetic field at ultra-low temperatures. At a low field of 0.2 T, a temperature-independent spin-lattice relaxation rate (
1/T1) over more than a decade confirms the presence of spinons. Below 0.4 K, an additional relaxation channel emerges, characterized by
1/T1∝T and a spectral weight growing as
−ln(T/T0), signaling a random-singlet ground state induced by weak quenched disorder. At fields above 0.5 T, a field-induced spin gap
Δ∝H2/3 observed in both
1/T1 and the Knight shift signifies soliton excitations. Our results establish copper benzoate as a unique experimental platform for studying one-dimensional quantum integrability and the interplay of disorder and correlations.