European Laboratory for Non-Linear Spectroscopy (LENS)
We report on the realization of a platform for trapping and manipulating individual 88^{88}Sr atoms in optical tweezers. A first cooling stage based on a blue magneto-optical trap (MOT) operating on the 1S0^1S_0 -> 1P1^1P_1 transition at 461 nm enables us to trap approximately 4×1064\times 10^6 atoms at a temperature of 8 mK. Further cooling is achieved in a narrow-line red MOT using the 1S0^1S_0 -> 3P1^3P_1 intercombination transition at 689 nm, bringing 4×1054\times 10^5 atoms down to 5 uK and reaching a density of 1010\approx 10^{10} cm3^{-3}. Atoms are then loaded into 813 nm tweezer arrays generated by crossed acousto-optic deflectors and tightly focused onto the atoms with a high-numerical-aperture objective. Through light-assisted collision processes we achieve the collisional blockade, which leads to single-atom occupancy with a probability of about 50%50\%. The trapped atoms are detected via fluorescence imaging with a fidelity of 99.986(6)%99.986(6)\%, while maintaining a survival probability of 97(1)%97(1)\%. The release-and-recapture measurement provides a temperature of 12.92(5)12.92(5) uK for the atoms in the tweezers, and the ultra-high-vacuum environment ensures a vacuum lifetime higher than 7 minutes. These results demonstrate a robust alkaline-earth tweezer platform that combines efficient loading, cooling, and high-fidelity detection, providing the essential building blocks for scalable quantum simulation and quantum information processing with Sr atoms.
Large-scale simulations of light-matter interaction in natural photosynthetic antenna complexes of the Chlorobium Tepidum green sulfur bacteria (GSB) containing more than one hundred thousand chlorophyll molecules, comparable with natural size, have been performed. Here we have modeled the entire process of the exciton energy transfer, from sunlight absorption to exciton trapping in the reaction centers (RCs) in presence of a thermal bath. The energy transfer has been analyzed using the radiative non-Hermitian Hamiltonian and solving the rate equations for the populations. Sunlight pumping has been modeled as black-body radiation with an attenuation factor that takes the Sun-Earth distance into account. Cylindrical structures typical of GSB antenna complexes, and the dimeric baseplate comparable to natural size have been considered. Our analysis shows that under natural sunlight, in photosynthetic antennae of GSB the number of excitations reaching the RC per unit time matches the RC closure rate and the internal efficiency shows values close to 80%\sim 80\%. We also considered cylindrical structures where the orientation of the dipoles does not reflect the natural one. Specifically, we vary continuously the angle of the transition dipole with respect to the cylinder main axis, focusing on the case where all dipoles are parallel to the cylinder axis. We also consider the important case where the dipoles are randomly oriented. In all cases the light-harvesting efficiency is lower than in the natural structure, showing the high sensitivity of light harvesting to the specific orientation of the dipole moments. Our results allow for a better understanding of the relationship between structure and functionality in photosynthetic antennae of GSB and could drive the design of efficient light-harvesting devices.
While for non-relativistic short-range interactions, the spread of information is local, remaining confined in an effective light cone, long-range interactions can generate either nonlocal (faster-than-ballistic) or local (ballistic) spread of correlations depending on the initial conditions. This makes long-range interactions a rich platform for controlling the spread of information. Here, we derive an effective Hamiltonian analytically and identify the specific interaction term that drives nonlocality in a wide class of long-range spin chains. This allows us to understand the conditions for the emergence of local behavior in the presence of nonlocal interactions and to identify a regime where the causal space-time landscape can be precisely designed. Indeed, we show that for large long-range interaction strength or large system size, initial conditions can be chosen in a way that allows a local perturbation to generate nonlocal signals at programmable distant positions, which then propagate within effective light cones. The possibility of engineering the emergence of nonlocal Lieb-Robinson-like light cones allows one to shape the causal landscape of long-range interacting systems, with direct applications to quantum information processing devices, quantum memories, error correction, and information transport in programmable quantum simulators.
In the Hall effect, a voltage drop develops perpendicularly to the current flow in the presence of a magnetic field, leading to a transverse Hall resistance. Recent developments with quantum simulators have unveiled strongly correlated and universal manifestations of the Hall effect. However, a direct measurement of the Hall voltage and of the Hall resistance in a non-electronic system of strongly interacting fermions was not achieved to date. Here, we demonstrate a technique for measuring the Hall voltage in a neutral-atom-based quantum simulator. From that we provide the first direct measurement of the Hall resistance in a cold-atom analogue of a solid-state Hall bar and study its dependence on the carrier density, along with theoretical analyses. Our work closes a major gap between analogue quantum simulations and measurements performed in solid-state systems, providing a key tool for the exploration of the Hall effect in highly tunable and strongly correlated systems.
Entanglement is an essential ingredient in many quantum communication protocols. In particular, entanglement can be exploited in quantum key distribution (QKD) to generate two correlated random bit strings whose randomness is guaranteed by the nonlocal property of quantum mechanics. Most of QKD protocols tested to date rely on polarization and/or time-bin encoding. Despite compatibility with existing fiber-optic infrastructure and ease of manipulation with standard components, frequency-bin QKD have not yet been fully explored. Here we report the first demonstration of entanglement-based QKD using frequency-bin encoding. We implement the BBM92 protocol using photon pairs generated by two independent, high-finesse, ring resonators on a silicon photonic chip. We perform a passive basis selection scheme and simultaneously record sixteen projective measurements. A key finding is that frequency-bin encoding is sensitive to the random phase noise induced by thermal fluctuations of the environment. To correct for this effect, we developed a real-time adaptive phase rotation of the measurement basis, achieving stable transmission over a 26 km fiber spool with a secure key rate >= 4.5 bit/s. Our work introduces a new degree of freedom for the realization of entangled based QKD protocols in telecom networks.
We theoretically investigate a single fluorescent molecule as a hybrid quantum optical device, in which multiple external laser sources exert control of the vibronic states. In the high-saturation regime, a coherent interaction is established between the vibrational and electronic degrees of freedom, and molecules can simulate several cavity QED models, whereby a specific vibrational mode plays the role of the cavity mode. Focusing on the specific example where the system is turned into an analogue simulator of the quantum Rabi model, the steady state exhibits vibrational bi-modality resulting in a statistical mixture of highly non-classical vibronic cat states. Applying our paradigm to molecules with prominent spatial asymmetry and combining an optical excitation with a THz(IR) driving, the system can be turned into a single photon transducer. Two possible implementations are discussed based on the coupling to a subwavelength THz patch antenna or a resonant metamaterial. In a nutshell, this work assesses the role of molecules as an optomechanical quantum toolbox for creating hybrid entangled states of electrons, photons, and vibrations, hence enabling frequency conversion over very different energy scales.
The successful development of future photonic quantum technologies heavily depends on the possibility of realizing robust, reliable and, crucially, scalable nanophotonic devices. In integrated networks, quantum emitters can be deployed as single-photon sources or non-linear optical elements, provided their transition linewidth is broadened only by spontaneous emission. However, conventional fabrication approaches are hardly scalable, typically detrimental for the emitter coherence properties and bear limitations in terms of geometries and materials. Here we introduce an alternative platform, based on molecules embedded in polymeric photonic structures. Three-dimensional patterns are achieved via direct laser writing around selected molecular emitters, which preserve near-Fourier-limited fluorescence. By using an integrated polymeric design, record-high photon fluxes from a single cold molecule are reported. The proposed technology allows to conceive a novel class of quantum devices, including integrated multi-photon interferometers, arrays of indistinguishable single photon sources and hybrid electro-optical nanophotonic devices.
Single molecules in solid-state matrices have been proposed as sources of single-photon Fock states back 20 years ago. Their success in quantum optics and in many other research fields stems from the simple recipes used in the preparation of samples, with hundreds of nominally identical and isolated molecules. Main challenges as of today for their application in photonic quantum technologies are the optimization of light extraction and the on-demand emission of indistinguishable photons. We here present Hong-Ou-Mandel experiments with photons emitted by a single molecule of dibenzoterrylene in an anthracene nanocrystal at 3 K, under continuous wave and also pulsed excitation. A detailed theoretical model is applied, which relies on independent measurements for most experimental parameters, hence allowing for an analysis of the different contributions to the two-photon interference visibility, from residual dephasing to spectral filtering.
Recent years have seen significant growth of quantum technologies, and specifically quantum sensing, both in terms of the capabilities of advanced platforms and their applications. One of the leading platforms in this context is nitrogen-vacancy (NV) color centers in diamond, providing versatile, high-sensitivity, and high-resolution magnetic sensing. Nevertheless, current schemes for spin resonance magnetic sensing (as applied by NV quantum sensing) suffer from tradeoffs associated with sensitivity, dynamic range, and bandwidth. Here we address this issue, and implement machine learning tools to enhance NV magnetic sensing in terms of the sensitivity/bandwidth tradeoff in large dynamic range scenarios. We experimentally demonstrate this new approach, reaching an improvement in the relevant figure of merit by a factor of up to 5. Our results promote quantum machine learning protocols for sensing applications towards more feasible and efficient quantum technologies.
We report on the realization of a platform for trapping and manipulating individual 88^{88}Sr atoms in optical tweezers. A first cooling stage based on a blue magneto-optical trap (MOT) operating on the 1S0^1S_0 -> 1P1^1P_1 transition at 461 nm enables us to trap approximately 4×1064\times 10^6 atoms at a temperature of 8 mK. Further cooling is achieved in a narrow-line red MOT using the 1S0^1S_0 -> 3P1^3P_1 intercombination transition at 689 nm, bringing 4×1054\times 10^5 atoms down to 5 uK and reaching a density of 1010\approx 10^{10} cm3^{-3}. Atoms are then loaded into 813 nm tweezer arrays generated by crossed acousto-optic deflectors and tightly focused onto the atoms with a high-numerical-aperture objective. Through light-assisted collision processes we achieve the collisional blockade, which leads to single-atom occupancy with a probability of about 50%50\%. The trapped atoms are detected via fluorescence imaging with a fidelity of 99.986(6)%99.986(6)\%, while maintaining a survival probability of 97(1)%97(1)\%. The release-and-recapture measurement provides a temperature of 12.92(5)12.92(5) uK for the atoms in the tweezers, and the ultra-high-vacuum environment ensures a vacuum lifetime higher than 7 minutes. These results demonstrate a robust alkaline-earth tweezer platform that combines efficient loading, cooling, and high-fidelity detection, providing the essential building blocks for scalable quantum simulation and quantum information processing with Sr atoms.
Large-scale simulations of light-matter interaction in natural photosynthetic antenna complexes of the Chlorobium Tepidum green sulfur bacteria (GSB) containing more than one hundred thousand chlorophyll molecules, comparable with natural size, have been performed. Here we have modeled the entire process of the exciton energy transfer, from sunlight absorption to exciton trapping in the reaction centers (RCs) in presence of a thermal bath. The energy transfer has been analyzed using the radiative non-Hermitian Hamiltonian and solving the rate equations for the populations. Sunlight pumping has been modeled as black-body radiation with an attenuation factor that takes the Sun-Earth distance into account. Cylindrical structures typical of GSB antenna complexes, and the dimeric baseplate comparable to natural size have been considered. Our analysis shows that under natural sunlight, in photosynthetic antennae of GSB the number of excitations reaching the RC per unit time matches the RC closure rate and the internal efficiency shows values close to 80%\sim 80\%. We also considered cylindrical structures where the orientation of the dipoles does not reflect the natural one. Specifically, we vary continuously the angle of the transition dipole with respect to the cylinder main axis, focusing on the case where all dipoles are parallel to the cylinder axis. We also consider the important case where the dipoles are randomly oriented. In all cases the light-harvesting efficiency is lower than in the natural structure, showing the high sensitivity of light harvesting to the specific orientation of the dipole moments. Our results allow for a better understanding of the relationship between structure and functionality in photosynthetic antennae of GSB and could drive the design of efficient light-harvesting devices.
Engineered ultracold atomic systems are a valuable platform for fundamental quantum mechanics studies and the development of quantum technologies. At near zero absolute temperature, atoms exhibit macroscopic phase coherence and collective quantum behavior, enabling their use in precision metrology, quantum simulation, and even information processing. This review provides an introductory overview of the key techniques used to trap, manipulate, and detect ultracold atoms, while highlighting the main applications of each method. We outline the principles of laser cooling, magnetic and optical trapping, and the most widely used techniques, including optical lattices and tweezers. Next, we discuss the manipulation methods of atomic internal and external degrees of freedom, and we present atom interferometry techniques and how to leverage and control interatomic interactions. Next, we review common ensemble detection strategies, including absorption and fluorescence imaging, state-selective readout, correlation and quantum non-demolition measurements and conclude with high-resolution approaches. This review aims to provide newcomers to the field with a broad understanding of the experimental toolkit that underpins research in ultracold atom physics and its applications across quantum science and technology.
The availability of data is limited in some fields, especially for object detection tasks, where it is necessary to have correctly labeled bounding boxes around each object. A notable example of such data scarcity is found in the domain of marine biology, where it is useful to develop methods to automatically detect submarine species for environmental monitoring. To address this data limitation, the state-of-the-art machine learning strategies employ two main approaches. The first involves pretraining models on existing datasets before generalizing to the specific domain of interest. The second strategy is to create synthetic datasets specifically tailored to the target domain using methods like copy-paste techniques or ad-hoc simulators. The first strategy often faces a significant domain shift, while the second demands custom solutions crafted for the specific task. In response to these challenges, here we propose a transfer learning framework that is valid for a generic scenario. In this framework, generated images help to improve the performances of an object detector in a few-real data regime. This is achieved through a diffusion-based generative model that was pretrained on large generic datasets. With respect to the state-of-the-art, we find that it is not necessary to fine tune the generative model on the specific domain of interest. We believe that this is an important advance because it mitigates the labor-intensive task of manual labeling the images in object detection tasks. We validate our approach focusing on fishes in an underwater environment, and on the more common domain of cars in an urban setting. Our method achieves detection performance comparable to models trained on thousands of images, using only a few hundreds of input data. Our results pave the way for new generative AI-based protocols for machine learning applications in various domains.
08 Apr 2025
A physics-constrained neural network is presented for predicting the optical response of metasurfaces. Our approach incorporates physical laws directly into the neural network architecture and loss function, addressing critical challenges in the modeling of metasurfaces. Unlike methods that require specialized weighting strategies or separate architectural branches to handle different data regimes and phase wrapping discontinuities, this unified approach effectively addresses phase discontinuities, energy conservation constraints, and complex gap-dependent behavior. We implement sine-cosine phase representation with Euclidean normalization as a non-trainable layer within the network, enabling the model to account for the periodic nature of phase while enforcing the mathematical constraint sin2ϕ+cos2ϕ=1\sin^2 \phi + \cos^2 \phi = 1. A Euclidean distance-based loss function in the sine-cosine space ensures a physically meaningful error metric while preventing discontinuity issues. The model achieves good, consistent performance with small, imbalanced datasets of 580 and 1075 data points, compared to several thousand typically required by alternative approaches. This physics-informed approach preserves physical interpretability while reducing reliance on large datasets and could be extended to other photonic structures by incorporating additional physical constraints tailored to specific applications.
Several quantum gravity scenarios lead to physics below the Planck scale characterised by nonlocal, Lorentz invariant equations of motion. We show that such non-local effective field theories lead to a modified Schr\"odinger evolution in the nonrelativistic limit. In particular, the nonlocal evolution of opto-mechanical quantum oscillators is characterised by a spontaneous periodic squeezing that cannot be generated by environmental effects. We discuss constraints on the nonlocality obtained by past experiments, and show how future experiments (already under construction) will either see such effects or otherwise cast severe bounds on the non-locality scale (well beyond the current limits set by the Large Hadron Collider). This paves the way for table top, high precision experiments on massive quantum objects as a promising new avenue for testing some quantum gravity phenomenology.
Anisotropic light transport is extremely common among scattering materials, yet a comprehensive picture of how macroscopic diffusion is determined by microscopic tensor scattering coefficients is not fully established yet. In this work, we present a theoretical and experimental study of diffusion in structurally anisotropic media with uniaxially symmetric scattering coefficients. Exact analytical relations are derived in the case of index-matched turbid media, unveiling the general relation between microscopic scattering coefficients and the resulting macroscopic diffusion tensor along different directions. Excellent agreement is found against anisotropic Monte Carlo simulations up to high degrees of anisotropy, in contrast with previously proposed approaches. The obtained solutions are used to analyze experimental measurements of anisotropic light transport in polystyrene foam samples under different degrees of uniaxial compression, providing a practical example of their applicability.
Passive radiative cooling technologies are highly attractive in pursuing sustainable development. However, current cooling materials are often static, which makes it difficult to cope with the varying needs of all-weather thermal comfort management. Herein, a strategy is designed to obtain flexible thermoplastic polyurethane nanofiber (Es-TPU) membranes via electrospinning, realizing reversible in-situ solvent-free switching between radiative cooling and solar heating through changes in its optical reflectivity by stretching. In its radiative cooling state (0% strain), the Es-TPU membrane shows a high and angular-independent reflectance of 95.6% in the 0.25-2.5 {\mu}m wavelength range and an infrared emissivity of 93.3% in the atmospheric transparency window (8-13 {\mu}m), reaching a temperature drop of 10 {\deg}C at midday, with a corresponding cooling power of 118.25 W/m2. The excellent mechanical properties of the Es-TPU membrane allows the continuous adjustment of reflectivity by reversibly stretching it, reaching a reflectivity of 61.1% ({\Delta}R=34.5%) under an elongation strain of 80%, leading to a net temperature increase of 9.5 {\deg}C above ambient of an absorbing substrate and an equivalent power of 220.34 W/m2 in this solar heating mode. The strong haze, hydrophobicity and outstanding aging resistance exhibited by this scalable membrane hold promise for achieving uniform illumination with tunable strength and efficient thermal management in practical applications.
Engineered dynamical maps combining coherent and dissipative transformations of quantum states with quantum measurements, have demonstrated a number of technological applications, and promise to be a crucial tool in quantum thermodynamic processes. Here, we exploit the control on the effective open spin qutrit dynamics of an NV center, to experimentally realize an autonomous feedback process (Maxwell demon) with tunable dissipative strength. The feedback is enabled by random measurement events that condition the subsequent dissipative evolution of the qutrit. The efficacy of the autonomous Maxwell demon is quantified by experimentally characterizing the fluctuations of the energy exchanged by the system with the environment by means of a generalized Sagawa-Ueda-Tasaki relation for dissipative dynamics. This opens the way to the implementation of a new class of Maxwell demons, which could be useful for quantum sensing and quantum thermodynamic devices.
We demonstrate an experimental technique to characterize genuinely nonclassical multi-time correlations using projective measurements with no ancillae. We implement the scheme in a nitrogen-vacancy center in diamond undergoing a unitary quantum work protocol. We reconstruct quantum-mechanical time correlations encoded in the Margenau-Hills quasiprobabilities. We observe work extraction peaks five times those of sequential projective energy measurement schemes and in violation of newly-derived stochastic bounds. We interpret the phenomenon via anomalous energy exchanges due to the underlying negativity of the quasiprobability distribution.
The recent development of Quantum Cascade Lasers (QCLs) represents one of the biggest opportunities for the deployment of a new class of Free Space Optical (FSO) communication systems working in the mid-infrared (Mid-IR) wavelength range. As compared to more common FSO systems exploiting the telecom range, the larger wavelength employed in Mid-IR systems delivers exceptional benefits in case of adverse atmospheric conditions, as the reduced scattering rate strongly suppresses detrimental effects on the FSO link length given by the presence of rain, dust, fog and haze. In this work, we use a novel FSO testbed operating at \SI{4.7}{\micro m}, to provide a detailed experimental analysis of noise regimes that could occur in realistic FSO Mid-IR systems based on QCLs. Our analysis reveals the existence of two distinct noise regions, corresponding to different realistic channel attenuation conditions, which are precisely controlled in our setup. To relate our results with real outdoor configurations, we combine experimental data with predictions of an atmospheric channel loss model, finding that error-free communication could be attained for effective distances up to 8~km in low visibility conditions of 1 km. Our analysis of noise regimes may have a key relevance for the development of novel, long-range FSO communication systems based on Mid-IR QCL sources
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